Scanning electron microscope image of restacked 1T phase 2D MoS 2 film.b, The electrochemical system consists of a working electrode (the actuator) along with a counter electrode (Pt) and a reference electrode (standard calomel electrode, SCE) submerged in 0.5 M H 2 SO 4 .c, Images of curvature induced by charge intercalation in free-standing (that is, no Kapton beam) 1T MoS 2 film on gold (scale bar, 1 cm).d,e, Diagram (d) and photograph (e) of actuation in forward and backward directions by modulation of the electrode potential between -0.3 V and + 0.3 V.
Invention Summary:Actuators that convert electrical energy to mechanical energy are useful in a wide variety of electromechanical systems and robotics. Nonporous metal as well as graphite have been implemented in actuation applications. Although high strains can be achieved, but actuation only operates at high voltages (3-3.4 V) and very low frequencies (mHz range).
Researchers at Rutgers University have invented a novel macroscopic actuation device made of (2D) 1T phase molybdenum disulfide (MoS 2 ) nanosheets-coated flexible films that can operate at low voltages (+0.3 to –0.3 V) and frequencies up to 1 Hz. The mechanism of actuation is the insertion and removal of cations between nanosheets of (2D) 1T phase MoS 2 under electrochemical induction of +0.3 to –0.3V. The MoS 2 films are able to generate mechanical stresses of ~ 17 MPa – higher than mammalian muscle (~0.3 MPa) and comparable to ceramic piezoelectric actuators (~ 40 MPa). The actuation performance is attributed to the high electrical conductivity of the metallic 1T phase of MoS 2 nanosheets, the elastic modulus of restacked MoS 2 layers and fast proton diffusion between the nanosheets.
Publication:
Metallic molybdenum disulfide nanosheet-based electrochemical actuators. Acerce M, Akdoğan EK and Chhowalla M. (2017)Nature549: 370-373.
Electromechanical systems and robotics such as steerable catheters for biomedical applications, adaptive wings for aircrafts, or drag-reducing wind turbines.
由于技术保密工作限制,技术信息无法完全展现,请通过邮箱或短信联系我们,获取更多技术资料。
metallic 1t phase
fast proton diffusion
electrochemical system consists
convert electrical energy
nanosheets-coated flexible films